Office 365 may block users from sending e-mails if they are suspected of being compromised. To see the list of users and remove them from the list:
https://security.microsoft.com/antispam
To set who gets a notification when a user is blocked:
https://security.microsoft.com/antispam
Anti-spam outbound policy (Default)
Edit Protection settings
Notify these users and groups if a sender is blocked due to sending outbound spam
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